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For the 2025-26 school year, there is 1 public school serving 226 students in Union Grove, NC (there are , serving 27 private students). 89% of all K-12 students in Union Grove, NC are educated in public schools (compared to the NC state average of 92%).

The top-ranked public school in Union Grove, NC is Union Grove Elementary School. Overall testing rank is based on a school's combined math and reading proficiency test score ranking.

Union Grove, NC public school have an average math proficiency score of 47% (versus the North Carolina public school average of 51%), and reading proficiency score of 42% (versus the 50% statewide average). Schools in Union Grove have an average ranking of 4/10, which is in the bottom 50% of North Carolina public schools.

Minority enrollment is 16% of the student body (majority Hispanic), which is less than the North Carolina public school average of 57% (majority Black and Hispanic).