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For the 2025-26 school year, there are 4 public schools serving 2,749 students in Centreville, MD (there are , serving 301 private students). 90% of all K-12 students in Centreville, MD are educated in public schools (compared to the MD state average of 86%).

The top ranked public schools in Centreville, MD are Kennard Elementary School, Queen Anne's County High School and Centreville Middle School. Overall testing rank is based on a school's combined math and reading proficiency test score ranking.

Centreville, MD public schools have an average math proficiency score of 33% (versus the Maryland public school average of 27%), and reading proficiency score of 55% (versus the 45% statewide average). Schools in Centreville have an average ranking of 6/10, which is in the top 50% of Maryland public schools.

Minority enrollment is 26% of the student body (majority Hispanic), which is less than the Maryland public school average of 68% (majority Black).